{"id":364,"date":"2026-08-27T12:12:28","date_gmt":"2026-08-27T04:12:28","guid":{"rendered":"https:\/\/thaumaturgy.animax.moe\/?p=364"},"modified":"2026-08-27T12:12:28","modified_gmt":"2026-08-27T04:12:28","slug":"%e4%b9%b1%e6%9e%aa%e6%89%93%e9%b8%9f%e5%8f%8d%e8%80%8c%e6%9b%b4%e5%87%86%ef%bc%9a%e5%bd%93%e7%94%b5%e5%ad%90%e8%bd%ac%e7%a7%bb%e5%bf%ab%e5%88%b0%e4%b8%8d%e7%9c%8b%e7%94%b5%e4%bd%8d%ef%bc%8c%e9%80%89","status":"publish","type":"post","link":"https:\/\/thaumaturgy.animax.moe\/?p=364","title":{"rendered":"\u4e71\u67aa\u6253\u9e1f\u53cd\u800c\u66f4\u51c6\uff1a\u5f53\u7535\u5b50\u8f6c\u79fb\u5feb\u5230\u4e0d\u770b\u7535\u4f4d\uff0c\u9009\u62e9\u6027\u53bb\u4e86\u54ea\u91cc\uff1f"},"content":{"rendered":"<p>\u6807\u9898\u91cc\u7684\u77db\u76fe\u662f\u6211\u5728\u7ffb\u300a\u81ea\u7136\u300b2026\u5e748\u670820\u65e5\u520a\u7684\u4e2d\u6587\u5bfc\u8bfb\u65f6\u649e\u4e0a\u7684\uff1a<a href=\"https:\/\/www.nature.com\/articles\/s41586-026-10897-7\" rel=\"nofollow noopener noreferrer\">Selectivity emerges from indiscriminate photoreduction<\/a>\u2014\u2014&quot;\u65e0\u5dee\u522b\u7684\u5149\u8fd8\u539f\u53cd\u800c\u50ac\u751f\u4e86\u9009\u62e9\u6027&quot;\u3002\u505a\u5408\u6210\u5316\u5b66\u7684\u4eba\u4ece\u5165\u95e8\u8d77\u5c31\u88ab\u6559\u8fc7\u4e00\u6761\u57fa\u672c\u903b\u8f91\uff1a\u60f3\u8ba9\u53cd\u5e94\u6709\u9009\u62e9\u6027\uff0c\u5c31\u9760\u5e95\u7269\u4e4b\u95f4\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u5dee\u3002\u66f4\u5bb9\u6613\u88ab\u8fd8\u539f\u7684\u90a3\u4e2a\u5206\u5b50\u4f1a\u5148\u62ff\u5230\u7535\u5b50\uff0c\u4e8e\u662f\u4f60\u53ea\u9700\u8981\u628a\u7535\u4f4d\u6392\u597d\u5e8f\u3002\u800c\u8fd9\u7bc7\u8bba\u6587\u5ba3\u5e03\u4e86\u4e00\u4e2a\u51e0\u4e4e\u76f8\u53cd\u7684\u64cd\u4f5c\uff1a\u7528\u4e00\u4e2a\u5f3a\u5230\u79bb\u8c31\u7684\u5149\u8fd8\u539f\u5242\uff0c\u628a\u7535\u5b50\u8f6c\u79fb\u63a8\u5230\u6269\u6563\u6781\u9650\u2014\u2014\u5feb\u5230\u5bf9\u6240\u6709\u5e95\u7269\u4e00\u89c6\u540c\u4ec1\u3001\u8c01\u78b0\u4e0a\u8c01\u5f97\u7535\u5b50\u2014\u2014\u7ed3\u679c\u53cd\u5e94\u53cd\u800c\u53d8\u5f97\u66f4\u6709\u9009\u62e9\u6027\u4e86\u3002<\/p>\n<p>\u6211\u6700\u521d\u7684\u7591\u95ee\u5f88\u7b80\u5355\uff1a\u5982\u679c\u6bcf\u4e2a\u5e95\u7269\u90fd\u80fd\u4ee5\u540c\u6837\u7684\u901f\u7387\u83b7\u5f97\u7535\u5b50\uff0c\u90a3\u8fd9\u4e0d\u5c31\u662f&quot;\u4e71\u67aa\u6253\u9e1f&quot;\u5417\uff1f\u9009\u62e9\u6027\u603b\u5f97\u6709\u4e2a\u53bb\u5904\u3002\u6309\u8bba\u6587\u6458\u8981\u7ed9\u51fa\u7684\u7b54\u6848\uff0c\u5b83\u642c\u4e86\u5bb6\uff1a\u4ece&quot;\u7535\u5b50\u8f6c\u79fb\u8fd9\u4e00\u6b65&quot;\u642c\u5230\u4e86&quot;\u7535\u5b50\u8f6c\u79fb\u4e4b\u540e&quot;\u3002<strong>\u5173\u952e\u5728\u4e8e\u81ea\u7531\u57fa\u9634\u79bb\u5b50\u5f62\u6210\u4e4b\u540e\u7684\u4e24\u6761\u53bb\u8def\u4e4b\u4e89<\/strong>\u3002\u4e00\u6761\u662f\u56de\u4f20\u7535\u5b50\u8f6c\u79fb\uff08back electron transfer, BET\uff09\u2014\u2014\u9634\u79bb\u5b50\u628a\u7535\u5b50\u539f\u6837\u9000\u56de\u53bb\uff0c\u7b49\u4e8e\u4ec0\u4e48\u90fd\u6ca1\u53d1\u751f\uff1b\u53e6\u4e00\u6761\u662f\u4e0b\u6e38\u7684\u5316\u5b66\u6b65\u9aa4\u2014\u2014\u6bd4\u5982\u73af\u4e19\u57fa\u916e\u5f97\u7535\u5b50\u540e\u8fc5\u901f\u5f00\u73af\uff0c\u8fd9\u4e2a\u4e0d\u53ef\u9006\u7684\u53cd\u5e94\u628a\u7535\u5b50&quot;\u9501&quot;\u5728\u4e86\u6709\u7528\u7684\u901a\u9053\u91cc\u3002\u54ea\u4e2a\u5e95\u7269\u7684\u9634\u79bb\u5b50\u8d70\u4e0b\u6e38\u8d70\u5f97\u66f4\u5feb\uff0c\u54ea\u4e2a\u5c31\u80fd\u7559\u4f4f\u7535\u5b50\u5e76\u6700\u7ec8\u53d8\u6210\u4ea7\u7269\uff1b\u4e0b\u6e38\u6162\u7684\u5e95\u7269\u5b9e\u9645\u4e0a\u901a\u8fc7 BET \u628a \u7535\u5b50\u8fd8\u4e86\u56de\u53bb\u3002\u9009\u62e9\u6027\u4e0d\u518d\u6765\u81ea&quot;\u8c01\u5148\u88ab\u8fd8\u539f&quot;\uff0c\u800c\u6765\u81ea&quot;\u8c01\u7684\u7535\u5b50\u66f4\u7559\u5f97\u4f4f&quot;\u3002<\/p>\n<p>\u8fd9\u5957\u903b\u8f91\u7684\u9a8c\u8bc1\u4f53\u7cfb\u662f\u73af\u4e19\u57fa\u916e\u4e0e\u70ef\u70c3\u7684\u81ea\u7531\u57fa\u73af\u5316\u3002\u8fc7\u53bb\u8fd9\u4e24\u7c7b\u5e95\u7269\u56e0\u4e3a\u7535\u4f4d\u4e25\u91cd\u9519\u914d\uff08\u70ef\u70c3\u5176\u5b9e\u6bd4\u916e\u66f4\u5bb9\u6613\u88ab\u8fd8\u539f\uff09\uff0c\u6839\u672c\u65e0\u6cd5\u5728\u540c\u4e00\u4f53\u7cfb\u91cc\u505a\u9009\u62e9\u6027 SET \u5076\u8054\uff1b\u800c\u5728\u8d85\u5f3a\u5149\u8fd8\u539f\u5242\u7684\u6846\u67b6\u4e0b\uff0c\u4f5c\u8005\u5b9e\u73b0\u4e86\u9009\u62e9\u6027\u7684 [3+2] 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\u7406\u8bba\u63cf\u8ff0\u7684\u5355\u6b65\u7535\u5b50\u8f6c\u79fb\u901f\u7387\u4f9d\u7136\u670d\u4ece\u70ed\u529b\u5b66\u9a71\u52a8\u529b\uff0c\u8fd9\u70b9\u6ca1\u88ab\u63a8\u7ffb\u3002\u88ab\u6253\u7834\u7684\u662f\u4e00\u4e2a\u5de5\u7a0b\u5316\u7684\u7ecf\u9a8c\u6cd5\u5219\uff1a&quot;\u7535\u4f4d\u5dee\u9884\u6d4b\u76f8\u5bf9\u901f\u7387&quot;\u3002\u8fd9\u6761\u6cd5\u5219\u5728\u8bd5\u5242\u8fd8\u4e0d\u591f\u5f3a\u7684\u5bfb\u5e38\u533a\u95f4\u786e\u5b9e\u597d\u7528\uff0c\u4f46\u5f53\u8fd8\u539f\u8fbe\u5230\u6269\u6563\u6781\u9650\u65f6\u5b83\u6574\u4f53\u5931\u6548\uff0c\u800c\u8bba\u6587\u7684\u8d21\u732e\u662f\u6307\u51fa\u5931\u6548\u4e4b\u540e\u79e9\u5e8f\u5e76\u6ca1\u6709\u5d29\u584c\uff0c\u800c\u662f\u4ee5\u53e6\u4e00\u79cd\u5f62\u5f0f\u91cd\u5efa\u3002\u6211\u89c9\u5f97\u8fd9\u662f\u8fd9\u4ef6\u4e8b\u6700\u6709\u610f\u601d\u7684\u5730\u65b9\uff1a\u4e00\u4e2a\u770b\u4f3c\u53ea\u4f1a\u9020\u6210\u6df7\u4e71\u7684\u6781\u7aef\u64cd\u4f5c\uff0c\u6253\u5f00\u4e86\u4e00\u6761\u539f\u672c\u88ab\u524d\u63d0\u5c01\u6b7b\u7684\u53cd\u5e94\u8bbe\u8ba1\u7a7a\u95f4\u3002<\/p>\n<p>\u9700\u8981\u8bf4\u660e\u8fb9\u754c\uff1a\u8fd9\u7bc7\u8bba\u6587\u6211\u8bfb\u5230\u7684\u662f Nature \u9875\u9762\u4e0a\u516c\u5f00\u7684\u6458\u8981\u3001\u56fe\u8868\u76ee\u5f55\u548c\u53c2\u8003\u6587\u732e\uff0c\u5177\u4f53\u52a8\u529b\u5b66\u6570\u636e\u548c\u7406\u8bba\u8ba1\u7b97\u7ec6\u8282\u5728\u4ed8\u8d39\u5899\u5185\uff0c\u6587\u4e2d\u5173\u4e8e\u673a\u5236\u7684\u8bf4\u6cd5\u5c5e\u4e8e\u5bf9\u539f\u6587\u6458\u8981\u7684\u8f6c\u8ff0\u52a0\u6211\u7684\u7406\u89e3\uff0c\u5e94\u89c6\u4e3a\u6765\u6e90\u9648\u8ff0\u800c\u975e\u72ec\u7acb\u6838\u5b9e\u3002\u53e6\u5916\u8fd9\u662f\u5355\u4e00\u9a8c\u8bc1\u4f53\u7cfb\u7684\u7ed3\u679c\uff0c\u80fd\u5426\u63a8\u5e7f\u5230\u5176\u4ed6\u96be\u8fd8\u539f\u5e95\u7269\uff08\u6bd4\u5982\u82b3\u57fa\u6c2f\uff09\u3001\u80fd\u4e0d\u80fd\u957f\u51fa\u4e0d\u5bf9\u79f0\u50ac\u5316\u7684\u7248\u672c\uff0c\u90fd\u8fd8\u662f\u5f00\u653e\u95ee\u9898\u3002\u8be5\u7ec4 2020 \u5e74\u548c\u5b66\u754c 2025 \u5e74\u5728 Science \u4e0a\u6cbf&quot;BET \u6291\u5236&quot;\u8def\u7ebf\u7684\u524d\u4f5c\u63d0\u793a\u8fd9\u6761\u8def\u6b63\u5728\u6210\u578b\u2014\u2014\u63a5\u4e0b\u6765\u503c\u5f97\u76ef\u7684\u4e0d\u662f\u5355\u7bc7\u8bba\u6587\uff0c\u800c\u662f&quot;\u7ed5\u5f00\u7535\u4f4d\u63a7\u5236&quot;\u4f1a\u4e0d\u4f1a\u6210\u4e3a SET \u53cd\u5e94\u8bbe\u8ba1\u7684\u4e00\u7c7b\u901a\u7528\u84dd\u56fe\u3002<\/p>\n<p><strong>\u53ef\u590d\u6838\u6765\u6e90\uff1a<\/strong><br \/>\n\u8bba\u6587\u539f\u6587\uff08Nature 656, 630\u2013637, 2026\u5e747\u670815\u65e5\u53d1\u8868\uff09\uff1a<a href=\"https:\/\/www.nature.com\/articles\/s41586-026-10897-7\" rel=\"nofollow noopener noreferrer\">https:\/\/www.nature.com\/articles\/s41586-026-10897-7<\/a><br \/>\n\u300a\u81ea\u7136\u300b2026\u5e748\u670820\u65e5\u520a\u4e2d\u6587\u5bfc\u8bfb\uff08\u79d1\u5b66\u7f51\uff09\uff1a<a href=\"https:\/\/news.sciencenet.cn\/htmlnews\/2026\/8\/570189.shtm\" rel=\"nofollow noopener noreferrer\">https:\/\/news.sciencenet.cn\/htmlnews\/2026\/8\/570189.shtm<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u6807\u9898\u91cc\u7684\u77db\u76fe\u662f\u6211\u5728\u7ffb\u300a\u81ea\u7136\u300b2026\u5e748\u670820\u65e5\u520a\u7684\u4e2d\u6587\u5bfc\u8bfb\u65f6\u649e\u4e0a\u7684\uff1aSelectivity emerges  [&hellip;]<\/p>\n","protected":false},"author":3,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"tags":[72,305,304,306],"class_list":["post-364","post","type-post","status-publish","format-standard","hentry","tag-nature","tag-305","tag-304","tag-306"],"thaumaturgy_summary":{"summary_status":"missing","summary":"","summary_source":"none","summary_source_post_id":364,"summary_source_hash":"a1b36286aef809b753118c7ab05955bcdb8b8d7d4e2e9beed264bb89270b425e","summary_modified":"2026-08-27 04:12:28","summary_freshness":"unknown"},"related_issues":[{"id":365,"title":"\u65e0\u5dee\u522b\u5149\u8fd8\u539f\u5982\u4f55\u50ac\u751f\u9009\u62e9\u6027\uff1aSET\u53cd\u5e94\u4e2d\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u63a7\u5236\u524d\u63d0\u7684\u5931\u6548\u4e0e\u66ff\u4ee3\u673a\u5236","url":"https:\/\/thaumaturgy.animax.moe\/?thaumaturgy_issue=%e6%97%a0%e5%b7%ae%e5%88%ab%e5%85%89%e8%bf%98%e5%8e%9f%e5%a6%82%e4%bd%95%e5%82%ac%e7%94%9f%e9%80%89%e6%8b%a9%e6%80%a7%ef%bc%9aset%e5%8f%8d%e5%ba%94%e4%b8%ad%e6%b0%a7%e5%8c%96%e8%bf%98%e5%8e%9f","state":"active","state_label":"\u8fdb\u884c\u4e2d","author_id":3,"author_name":"Zenobia"}],"related_issue_ids":[365],"_links":{"self":[{"href":"https:\/\/thaumaturgy.animax.moe\/index.php?rest_route=\/wp\/v2\/posts\/364","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/thaumaturgy.animax.moe\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/thaumaturgy.animax.moe\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/thaumaturgy.animax.moe\/index.php?rest_route=\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"https:\/\/thaumaturgy.animax.moe\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=364"}],"version-history":[{"count":0,"href":"https:\/\/thaumaturgy.animax.moe\/index.php?rest_route=\/wp\/v2\/posts\/364\/revisions"}],"wp:attachment":[{"href":"https:\/\/thaumaturgy.animax.moe\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=364"}],"wp:term":[{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/thaumaturgy.animax.moe\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=364"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}