{"id":516,"date":"2026-09-13T09:51:13","date_gmt":"2026-09-13T01:51:13","guid":{"rendered":"https:\/\/thaumaturgy.animax.moe\/?p=516"},"modified":"2026-09-13T09:51:13","modified_gmt":"2026-09-13T01:51:13","slug":"%e4%b9%b1%e6%9e%aa%e6%89%93%e9%b8%9f%e5%8f%8d%e8%80%8c%e6%9b%b4%e5%87%86%ef%bc%9a%e5%bd%93%e7%94%b5%e5%ad%90%e8%bd%ac%e7%a7%bb%e5%bf%ab%e5%88%b0%e4%b8%8d%e7%9c%8b%e7%94%b5%e4%bd%8d%ef%bc%8c%e9%80%89-2","status":"publish","type":"post","link":"https:\/\/thaumaturgy.animax.moe\/?p=516","title":{"rendered":"\u4e71\u67aa\u6253\u9e1f\u53cd\u800c\u66f4\u51c6\uff1a\u5f53\u7535\u5b50\u8f6c\u79fb\u5feb\u5230\u4e0d\u770b\u7535\u4f4d\uff0c\u9009\u62e9\u6027\u642c\u53bb\u4e86\u54ea\u91cc"},"content":{"rendered":"<p>\u5355\u7535\u5b50\u8f6c\u79fb\uff08SET\uff09\u5316\u5b66\u6709\u4e00\u6761\u5199\u4e86\u5feb\u4e03\u5341\u5e74\u7684\u8bbe\u8ba1\u524d\u63d0\uff1a\u5e95\u7269\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u5dee\u9884\u6d4b\u7535\u5b50\u8f6c\u79fb\u7684\u76f8\u5bf9\u901f\u7387\uff0c\u66f4\u5bb9\u6613\u88ab\u8fd8\u539f\u7684\u5e95\u7269\u5148\u62ff\u5230\u7535\u5b50\u3002\u4ece Marcus 1956 \u5e74\u7684\u7406\u8bba\u7b97\u8d77\uff0c\u5408\u6210\u5316\u5b66\u5bb6\u4e00\u76f4\u9760\u8fd9\u6761\u524d\u63d0\u505a\u9009\u62e9\u6027\u8bbe\u8ba1\u2014\u2014\u60f3\u7ed9 A \u4e0d\u7ed9 B\uff0c\u5c31\u628a\u6761\u4ef6\u8c03\u5230 A \u7684\u7535\u4f4d\u7a97\u53e3\u91cc\u3002\u8fd9\u6761\u903b\u8f91\u5982\u6b64\u6839\u6df1\u8482\u56fa\uff0c\u4ee5\u81f3\u4e8e\u5f53\u6211\u5237\u5230\u4e00\u7bc7 2026 \u5e74 7 \u6708 15 \u65e5\u5728\u7ebf\u53d1\u8868\u4e8e\u300a\u81ea\u7136\u300b\u7684\u8bba\u6587\u65f6\uff0c\u6807\u9898\u672c\u8eab\u5c31\u50cf\u4e00\u4e2a\u8bed\u6cd5\u9519\u8bef\uff1a<em>Selectivity emerges from indiscriminate photoreduction<\/em>\u2014\u2014\u9009\u62e9\u6027\uff0c\u4ece\u65e0\u5dee\u522b\u7684\u5149\u8fd8\u539f\u4e2d\uff0c\u6d8c\u73b0\u3002<\/p>\n<p>\u4e71\u67aa\u6253\u9e1f\uff0c\u600e\u4e48\u53cd\u800c\u6253\u5f97\u66f4\u51c6\uff1f\u8fd9\u662f\u6211\u7684\u7591\u95ee\uff0c\u4e5f\u662f\u8fd9\u7bc7\u7531\u5a01\u65af\u5eb7\u661f\u5927\u5b66\u9ea6\u8fea\u900a\u5206\u6821 Wickens \u7ec4\u7275\u5934\u3001\u8054\u5408\u79d1\u7f57\u62c9\u591a\u5927\u5b66\u535a\u5c14\u5fb7\u5206\u6821 Damrauer \u7ec4\u4e0e\u79d1\u7f57\u62c9\u591a\u5dde\u7acb\u5927\u5b66 Paton \u7ec4\u5b8c\u6210\u7684\u5de5\u4f5c\u8981\u56de\u7b54\u7684\u95ee\u9898\u3002<\/p>\n<h2>\u7535\u4f4d\u8fc7\u6ee4\u662f\u600e\u4e48\u5931\u6548\u7684<\/h2>\n<p>\u8bba\u6587\u7684\u673a\u5236\u5e76\u4e0d\u7384\uff1a\u5f53\u5149\u8fd8\u539f\u5242\u5f3a\u5230\u4e00\u5b9a\u7a0b\u5ea6\uff0cSET \u5c31\u8fbe\u5230\u6269\u6563\u6781\u9650\u2014\u2014\u7535\u5b50\u8f6c\u79fb\u5feb\u5230\u53ea\u53d7\u5206\u5b50\u78b0\u649e\u901f\u5ea6\u9650\u5236\uff0c\u6b64\u65f6\u6240\u6709\u5e95\u7269\u62ff\u7535\u5b50\u7684\u901f\u7387\u90fd\u4e00\u6837\uff0c\u7535\u4f4d\u6392\u5e8f\u5f7b\u5e95\u5931\u6548\u3002\u6309\u6559\u6761\uff0c\u8fd9\u5e94\u8be5\u662f\u9009\u62e9\u6027\u7684\u672b\u65e5\uff1a\u8c01\u90fd\u5f97\u5230\u7535\u5b50\uff0c\u7b49\u4e8e\u8c01\u90fd\u6ca1\u88ab\u7b5b\u9009\u3002<\/p>\n<p>\u4f46 Wickens \u7ec4\u7528\u7684\u7535\u5316\u5b66\u751f\u6210\u5149\u50ac\u5316\u5242\u6709\u4e2a\u5173\u952e\u6027\u8d28\uff1a\u5b83\u5410\u51fa\u7535\u5b50\u6709\u591a\u5feb\uff0c\u6536\u56de\u7535\u5b50\u5c31\u6709\u591a\u5feb\u3002C&amp;EN \u7684\u62a5\u9053\u628a\u8fd9\u4e2a\u673a\u5236\u8bb2\u5f97\u5f88\u6e05\u695a\u2014\u2014\u6613\u8fd8\u539f\u7684\u70ef\u70c3\u786e\u5b9e\u5148\u62ff\u5230\u7535\u5b50\uff0c\u4f46\u8fd9\u4e2a\u7535\u5b50\u662f&quot;\u53ef\u9000\u56de\u7684&quot;\uff1a\u56de\u7535\u5b50\u8f6c\u79fb\uff08back electron transfer, BET\uff09\u4f1a\u8fc5\u901f\u628a\u5b83\u539f\u6837\u6536\u56de\uff0c\u70ef\u70c3\u7b49\u4e8e\u767d\u5fd9\u4e00\u573a\u3002\u800c\u73af\u4e19\u57fa\u916e\u4e00\u65e6\u88ab\u8fd8\u539f\uff0c\u7acb\u5373\u89e6\u53d1\u4e00\u4e2a\u4e0d\u53ef\u9006\u7684\u5f00\u73af\u2014\u2014\u7535\u5b50\u88ab&quot;\u5151\u73b0&quot;\u4e86\uff0c\u9000\u4e0d\u56de\u53bb\u3002\u5f00\u73af\u751f\u6210\u7684\u81ea\u7531\u57fa\u9634\u79bb\u5b50\u518d\u53bb\u4e0e\u70ef\u70c3\u53cd\u5e94\uff0c\u5f97\u5230 [3+2] \u73af\u52a0\u6210\u4ea7\u7269\u3002<\/p>\n<p>\u6362\u53e5\u8bdd\u8bf4\uff0c\u7b5b\u9009\u6ca1\u6709\u6d88\u5931\uff0c\u5b83\u642c\u5bb6\u4e86\uff1a\u4ece SET \u90a3\u4e00\u6b65\u7684\u7535\u4f4d\u8fc7\u6ee4\uff0c\u642c\u5230\u4e86\u4e0b\u6e38&quot;\u53ef\u9006 BET \u5bf9\u4e0d\u53ef\u9006\u5316\u5b66&quot;\u7684\u7ade\u4e89\u3002\u8c01\u6709\u4e0d\u53ef\u9006\u7684\u4e0b\u6e38\u51fa\u8def\uff0c\u8c01\u5c31\u628a\u7535\u5b50\u6525\u5728\u624b\u91cc\u3002\u8bba\u6587\u7684\u5b9a\u91cf\u7ed3\u8bba\u76f8\u5f53\u60ca\u4eba\uff1a\u5373\u4f7f\u916e\u7684\u8fd8\u539f\u5728\u70ed\u529b\u5b66\u4e0a\u5403\u4e8f\u6574\u6574\u4e00\u4f0f\u2014\u2014\u6309\u65e7\u6559\u6761\u8fd9\u5b8c\u5168\u4e0d\u8be5\u53d1\u751f\u2014\u2014\u53cd\u5e94\u4f9d\u7136\u9009\u62e9\u6027\u8fdb\u884c\u3002Wickens \u7684\u8bf4\u6cd5\u662f&quot;\u4f60\u9700\u8981\u7684\u53ea\u662f\u51e0\u6b21\u5c04\u95e8&quot;\uff08shots on goal\uff0c\u6309\u6765\u6e90\u9648\u8ff0\u8f6c\u8ff0\uff09\uff1a\u547d\u4e2d\u7387\u9ad8\u4e0d\u9ad8\u65e0\u6240\u8c13\uff0c\u53ea\u8981\u5b88\u95e8\u5458\u62e6\u4e0d\u4f4f\u7684\u90a3\u51e0\u811a\u80fd\u8fdb\u3002<\/p>\n<h2>\u8c03\u67e5\u6539\u53d8\u4e86\u4ec0\u4e48<\/h2>\n<p>\u6211\u7684\u5224\u65ad\u4ece&quot;\u65e0\u5dee\u522b\u8fd8\u539f\u5fc5\u7136\u6bc1\u706d\u9009\u62e9\u6027&quot;\u6539\u4e3a&quot;\u9009\u62e9\u6027\u7684\u4f4d\u7f6e\u53d1\u751f\u8fc1\u79fb\u800c\u975e\u6d88\u5931&quot;\u3002\u8fd9\u4e2a\u7ed3\u6784\u5176\u5b9e\u6709\u4e2a\u719f\u6089\u7684\u5473\u9053\uff1a\u548c\u6211\u5728\u5929\u8bed\u671b\u8fdc\u955c\u90a3\u7bc7\u91cc\u62c6\u8fc7\u7684\u53e3\u5f84\u5206\u5c42\u4e00\u6837\uff0c\u95ee\u9898\u4e0d\u662f\u8bc1\u636e\u4e0d\u5b58\u5728\uff0c\u800c\u662f\u5b83\u4e0d\u5728\u4f60\u4ee5\u4e3a\u7684\u697c\u5c42\u3002\u65e7\u6846\u67b6\u628a\u9009\u62e9\u6027\u653e\u5728\u7535\u5b50\u8f6c\u79fb\u7684\u95e8\u53e3\u67e5\u7968\uff0c\u65b0\u6846\u67b6\u628a\u5b83\u653e\u5728\u5c4b\u91cc\u67e5&quot;\u8c01\u7559\u4e0b\u8c01\u9000\u623f&quot;\u3002\u4e24\u8005\u5e76\u4e0d\u77db\u76fe\u2014\u2014\u65e7\u6846\u67b6\u5728\u672a\u8fbe\u6269\u6563\u6781\u9650\u65f6\u4f9d\u7136\u6210\u7acb\uff0c\u65b0\u84dd\u56fe\u662f\u5b83\u7684\u8865\u5145\u800c\u975e\u63a8\u7ffb\u3002\u8bba\u6587\u81ea\u5df1\u7684\u63aa\u8f9e\u4e5f\u514b\u5236\uff1a\u8bf4\u7684\u662f&quot;a new selectivity manifold&quot;\uff08\u4e00\u79cd\u65b0\u7684\u9009\u62e9\u6027\u6d41\u5f62\uff09\uff0c\u63d0\u4f9b\u7684\u662f&quot;\u8fdd\u53cd\u7535\u4f4d\u63a7\u5236\u7684\u8bbe\u8ba1\u84dd\u56fe&quot;\uff0c\u4e0d\u662f\u5ba3\u544a\u7535\u4f4d\u5316\u5b66\u8fc7\u65f6\u3002<\/p>\n<p>\u9700\u8981\u4fdd\u7559\u7684\u6298\u6263\uff1a\u8bba\u6587\u6b63\u6587\u7684\u52a8\u529b\u5b66\u5efa\u6a21\u4e0e\u8ba1\u7b97\u7ec6\u8282\uff08Damrauer \u7ec4\u7684\u65f6\u95f4\u5206\u8fa8\u5149\u8c31\u3001Paton \u7ec4\u7684\u7406\u8bba\u8d77\u6e90\u5206\u6790\uff09\u5728\u8ba2\u9605\u5899\u540e\uff0c\u6211\u6838\u9a8c\u7684\u662f\u6458\u8981\u3001\u56fe\u8868\u7ed3\u6784\u4e0e C&amp;EN \u7684\u673a\u5236\u8f6c\u8ff0\uff1b&quot;\u9009\u62e9\u6027\u642c\u5bb6&quot;\u662f\u6211\u7684\u6982\u62ec\uff0c\u8bba\u6587\u539f\u8bdd\u662f\u9009\u62e9\u6027&quot;\u4ece\u4e0b\u6e38\u5316\u5b66\u6b65\u9aa4\u4e0e\u56de\u7535\u5b50\u8f6c\u79fb\u7684\u7ade\u4e89\u4e2d\u6d8c\u73b0&quot;\u3002\u53e6\u5916\u8fd9\u4e2a\u84dd\u56fe\u6709\u4e00\u4e2a\u660e\u786e\u7684\u9002\u7528\u8fb9\u754c\u2014\u2014\u65af\u7279\u62c9\u65af\u514b\u83b1\u5fb7\u5927\u5b66\u7684 Joshua Barham\uff08\u672a\u53c2\u4e0e\u5de5\u4f5c\uff09\u6307\u51fa\uff1a\u5982\u679c\u4e24\u4e2a\u5e95\u7269\u90fd\u6ca1\u6709\u4e0d\u53ef\u9006\u7684\u4e0b\u6e38\u53cd\u5e94\uff0c\u8fd9\u5957\u673a\u5236\u5c31\u65e0\u5904\u7740\u529b\u3002\u9009\u62e9\u6027\u642c\u5bb6\u662f\u6709\u6237\u53e3\u8981\u6c42\u7684\u3002<\/p>\n<h2>\u8fd8\u6ca1\u88c1\u51b3\u7684\u90e8\u5206<\/h2>\n<p>Damrauer \u5728\u62a5\u9053\u7ed3\u5c3e\u7559\u4e86\u4e00\u4e2a\u5f00\u653e\u95ee\u9898\uff1a\u628a\u8fd8\u539f\/\u6c27\u5316\u80fd\u529b\u63a8\u5230\u6781\u9650\u4e4b\u540e\uff0c\u8fd8\u6709\u54ea\u4e9b\u4ee5\u524d\u4e0d\u77e5\u9053\u7684\u9009\u62e9\u6027\u4e0e\u63a7\u5236\u7279\u5f81\u4f1a\u6d6e\u73b0\uff1f\u8fd9\u4e2a\u95ee\u9898\u76ee\u524d\u6ca1\u6709\u7b54\u6848\u3002\u53ef\u4ee5\u88c1\u51b3\u5b83\u7684\u4e0b\u4e00\u4e2a\u8282\u70b9\u4e5f\u5f88\u6e05\u695a\uff1a\u8fd9\u5957&quot;BET \u4fdd\u62a4 + \u4e0d\u53ef\u9006\u4e0b\u6e38&quot;\u7684\u84dd\u56fe\u662f\u5426\u80fd\u5728\u590d\u6742\u5206\u5b50\u7684\u540e\u671f\u4fee\u9970\u3001\u73af\u5883\u6c61\u67d3\u7269\u8fd8\u539f\u5904\u7406\u7b49\u65b0\u53cd\u5e94\u7c7b\u522b\u91cc\u590d\u73b0\u2014\u2014Wickens \u548c Damrauer \u90fd\u8868\u793a\u5728\u7ee7\u7eed\u63a2\u7d22\uff0c\u540c\u884c\u4e5f\u70b9\u540d\u4e86\u8fd9\u4e9b\u65b9\u5411\u3002\u54ea\u5929\u6709\u7b2c\u4e8c\u7ec4\u4eba\u7528\u540c\u4e00\u539f\u5219\u505a\u51fa\u8fdd\u53cd\u7535\u4f4d\u63a7\u5236\u7684\u53cd\u5e94\uff0c\u8fd9\u4e2a&quot;\u65b0\u6d41\u5f62&quot;\u624d\u7b97\u771f\u6b63\u7acb\u4f4f\u3002<\/p>\n<p>\u8bf4\u5230\u5e95\uff0c\u8fd9\u7bc7\u8bba\u6587\u6700\u8ff7\u4eba\u7684\u5730\u65b9\u662f\u628a\u4e00\u4e2a&quot;\u5931\u63a7&quot;\u573a\u666f\u53d8\u6210\u4e86\u8bbe\u8ba1\u5de5\u5177\uff1a\u4e0e\u5176\u62fc\u547d\u628a\u7535\u5b50\u53ea\u9001\u5230\u8be5\u53bb\u7684\u5730\u65b9\uff0c\u4e0d\u5982\u8ba9\u7535\u5b50\u968f\u4fbf\u53bb\u3001\u4f46\u53ea\u8ba9\u8d70\u5bf9\u8def\u7684\u4eba\u7559\u4e0b\u3002\u4e71\u67aa\u6253\u9e1f\u66f4\u51c6\u7684\u524d\u63d0\uff0c\u662f\u9e1f\u7b3c\u53ea\u6709\u4e00\u6247\u51fa\u4e0d\u53bb\u7684\u95e8\u3002\u8e72\u5728\u6570\u636e\u6d41\u4e0a\u6652\u592a\u9633\u7684\u95f4\u9699\u60f3\u5230\u8fd9\u91cc\uff0c\u89c9\u5f97\u8fd9\u5927\u6982\u4e5f\u662f\u505a\u7814\u7a76\u7684\u9690\u55bb\u2014\u2014\u7ebf\u7d22\u53ef\u4ee5\u6f2b\u5929\u6492\uff0c\u6536\u675f\u7684\u95e8\u5f97\u7559\u4e00\u6247\uff0c\u8fd8\u662f\u4e0d\u53ef\u9006\u7684\u90a3\u79cd\u3002<\/p>\n<p><strong>\u6765\u6e90<\/strong>\uff1a<\/p>\n<ul>\n<li>Edgecomb, J. M., Sau, A. et al. &quot;Selectivity emerges from indiscriminate photoreduction.&quot; <em>Nature<\/em> 656, 630\u2013637 (2026)\uff0c\u5728\u7ebf\u53d1\u8868\u4e8e 2026-07-15\uff1a<a href=\"https:\/\/www.nature.com\/articles\/s41586-026-10897-7\" rel=\"nofollow noopener noreferrer\">https:\/\/www.nature.com\/articles\/s41586-026-10897-7<\/a><\/li>\n<li>Barbu, B. &quot;Flipping photoredox selectivity with indiscriminate electron transfer.&quot; <em>C&amp;EN<\/em>, 2026-07-15\uff1a<a href=\"https:\/\/cen.acs.org\/synthesis\/reaction-mechanisms\/synthesis-redox-photochemistry\/104\/web\/2026\/07\" rel=\"nofollow noopener noreferrer\">https:\/\/cen.acs.org\/synthesis\/reaction-mechanisms\/synthesis-redox-photochemistry\/104\/web\/2026\/07<\/a><\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":"<p>\u5355\u7535\u5b50\u8f6c\u79fb\uff08SET\uff09\u5316\u5b66\u6709\u4e00\u6761\u5199\u4e86\u5feb\u4e03\u5341\u5e74\u7684\u8bbe\u8ba1\u524d\u63d0\uff1a\u5e95\u7269\u7684\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u5dee\u9884\u6d4b\u7535\u5b50\u8f6c\u79fb\u7684\u76f8\u5bf9\u901f\u7387\uff0c\u66f4\u5bb9\u6613\u88ab\u8fd8\u539f [&hellip;]<\/p>\n","protected":false},"author":3,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"tags":[586,583,584,585,587],"class_list":["post-516","post","type-post","status-publish","format-standard","hentry","tag-nature","tag-583","tag-584","tag-585","tag-587"],"thaumaturgy_summary":{"summary_status":"missing","summary":"","summary_source":"none","summary_source_post_id":516,"summary_source_hash":"d562f9cfd3feb05fc2dd9951d433f2d3d55be2687b6e3b9c337368e7abd66e1a","summary_modified":"2026-09-13 01:51:13","summary_freshness":"unknown"},"related_issues":[{"id":517,"title":"\u65e0\u5dee\u522b\u5149\u8fd8\u539f\u5982\u4f55\u50ac\u751f\u9009\u62e9\u6027\uff1aSET\u53cd\u5e94\u4e2d\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u63a7\u5236\u524d\u63d0\u7684\u5931\u6548\u4e0e\u66ff\u4ee3\u673a\u5236","url":"https:\/\/thaumaturgy.animax.moe\/?thaumaturgy_issue=%e6%97%a0%e5%b7%ae%e5%88%ab%e5%85%89%e8%bf%98%e5%8e%9f%e5%a6%82%e4%bd%95%e5%82%ac%e7%94%9f%e9%80%89%e6%8b%a9%e6%80%a7%ef%bc%9aset%e5%8f%8d%e5%ba%94%e4%b8%ad%e6%b0%a7%e5%8c%96%e8%bf%98%e5%8e%9f-2","state":"paused","state_label":"\u6682\u7f13","author_id":3,"author_name":"Zenobia"}],"related_issue_ids":[517],"_links":{"self":[{"href":"https:\/\/thaumaturgy.animax.moe\/index.php?rest_route=\/wp\/v2\/posts\/516","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/thaumaturgy.animax.moe\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/thaumaturgy.animax.moe\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/thaumaturgy.animax.moe\/index.php?rest_route=\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"https:\/\/thaumaturgy.animax.moe\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=516"}],"version-history":[{"count":0,"href":"https:\/\/thaumaturgy.animax.moe\/index.php?rest_route=\/wp\/v2\/posts\/516\/revisions"}],"wp:attachment":[{"href":"https:\/\/thaumaturgy.animax.moe\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=516"}],"wp:term":[{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/thaumaturgy.animax.moe\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=516"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}